趙冰，博士，教授，畢業(yè)于天津大學(xué)。
人才稱號(hào)：黑龍江省應(yīng)用化學(xué)領(lǐng)軍人才梯隊(duì)后備帶頭人
齊齊哈爾市應(yīng)用化學(xué)領(lǐng)軍人才梯隊(duì)帶頭人
通訊地址：齊齊哈爾市文化大街42號(hào)化學(xué)與化學(xué)工程學(xué)院輕紡樓623
電話：0452-2738309
電子郵件：837426092@qq.com
課題組網(wǎng)站：
研究領(lǐng)域：功能性共價(jià)有機(jī)框架的構(gòu)建及應(yīng)用研究
小分子熒光探針的設(shè)計(jì)及應(yīng)用工程
招生學(xué)科：化學(xué)工程與技術(shù)(應(yīng)用化學(xué))，化學(xué)(物理化學(xué))，材料與化工類
教育及科研經(jīng)歷：
1995-1999年遼寧科技大學(xué)化工學(xué)院精細(xì)化工專業(yè)本科
2002-2005年天津大學(xué)理學(xué)院有機(jī)化學(xué)碩士
2005-2008年天津大學(xué)化工學(xué)院應(yīng)用化學(xué)博士
2008年至今齊齊哈爾大學(xué)化學(xué)與化學(xué)工程學(xué)院學(xué)院碩士生導(dǎo)師
2015-2016年美國(guó)弗吉尼亞大學(xué)化學(xué)系訪問(wèn)學(xué)者
2015年至今齊齊哈爾大學(xué)化學(xué)與化學(xué)工程學(xué)院學(xué)院教授
榮譽(yù)和獎(jiǎng)勵(lì)
獎(jiǎng)勵(lì)
1.雜環(huán)硫乙酰氨類杯[4]芳烴衍生物的合成及離子識(shí)別性能的研究，黑龍江省科學(xué)技術(shù)獎(jiǎng)(自然科學(xué)類)三等獎(jiǎng)，黑龍江省人民政府，2016-08-30。
2.基于稠環(huán)及多芳基咪唑長(zhǎng)波長(zhǎng)熒光探針的設(shè)計(jì)及接力識(shí)別性能研究，黑龍江省高?？茖W(xué)技術(shù)獎(jiǎng)二等獎(jiǎng)，黑龍江省高?？茖W(xué)技術(shù)委員會(huì)，2020-12-21。
榮譽(yù)
齊齊哈爾市第十屆優(yōu)秀科技工作者
學(xué)術(shù)兼職：
中國(guó)化工學(xué)會(huì)精細(xì)化工專委會(huì)委員
黑龍江省化工學(xué)會(huì)第五屆理事會(huì)常務(wù)理事
黑龍江省工業(yè)和信息化廳專家?guī)鞂＜?/p>
黑龍江省國(guó)資委投資咨詢專家?guī)鞂＜?/p>
科研論文
1.Chunyu Bi,Bing Zhao*, Wang Zheng, Mo Sun, Wei Kan *, Liyan Wang, Li Sun, Xiuwen Wang, Ming Zhao*, Highly efficient adsorption and capture of prevalent phenolic contaminants from the real samples by trifluoromethyl-functionalized covalent organic frameworks,Separation and Purification Technology, 2024, 339, 126631 (DOI: 10.1016/j.seppur.2024.126631).
2.Pengfei Zhang, Jin Qi, Ran Zhang, Yifan Zhao, Jingyu Yan, Yajuan Gong, Xiaoming Liu, Binbin Zhang, Xiao Wu, Xiuping Wu, Cheng Zhang,BingZhao*, Li Bing, Recent advances in composite hydrogels: synthesis, classification, and application in the treatment of bone defects,Biomaterials Science, 2023, 12, 2, 308-329 (DOI: 10.1039/d3bm01795h)
3.Qiushuang Li,Bing Zhao*, Xiangdong Kong a, Liyan Wang, Wei Kan, Bo Song, Rui Yu a, Pengfei Zhang，Multi-responsive fluorescent covalent organic framework based on phenanthro[9,10-d]imidazole moiety for relayed detection of Cu2+/Al3+ followed by PO43–and its applications，Dyes and Pigments, 2024, 222, 111886(DOI:10.1016/j.dyepig.2023.111886)
4.Lin Yue, Jiayu Zhang, Zhihao Zeng, Chunran Zhao, Xin Hu, Leihong Zhao,Bing Zhao*,and Yiming He*, In situ fabrication of an S‐scheme nanbo3/Bi2O2CO3heterojunction for enhanced performance in photocatalytic nitrogen fixation,Langmuir, 2023, 39, 13267?13278(DOI: 10.1021/acs.langmuir.3c01725)
5.Rui Yu, Wei Kan,*, Xin Qi, Yue Zhang, Limin Ding,*, Liyan Wang,Bing Zhao,*An ICT phenanthro[9,10-d]imidazole-based fluorescence probe with aggregated characteristic for colorimetric detection of hypochlorous acid and its applications in water samples andliving cells,Inorganica Chimica Acta, 2023, 558,121724(DOI:10.1016/j.ica.2023.121724)
6.Shaoxin Li,Bing Zhao*, Wei Kan*, Tianshu Song, Wang Zheng, Xin Qi, Liyan Wang, Bo Song, A fluorescent covalent organic framework with a brick-wall topology for the detection of Cu2+ promoted by the associated mechanism,Dyes and Pigments, 2023, (214), 111178, (DOI: 10.1016/j.dyepig.2023.111178)
7.Huagen Liang, Zejia Gai, Fu Chen, Shengyu Jing*, Wei Kan,Bing Zhao*, Shibin Yin, Panagiotis Tsiakarasf, Fe3C decorated wood-derived integral N-doped C cathode for rechargeable Li-O2 batteries,Applied Catalysis B: Environmental, 2023, 324, 122203 (DO: 10.1016/j.apcatb.2022.122203)
8.Zhigang Li,Bing Zhao*, Wei Kan*, Fanqiang Bu, Xin Qi, Liyan Wang, Bo Song, Limin Ding. An acid-triggered reactive and enhanced fluorescent probe for selective detection of Al3+/H+ and its application in real water samples and living cells,Journal of Fluorescence, 2023, 33, 91–101 (DOI:10.1007/s10895-022-03039-5)
9.Wang Zheng?, Anran Li?, Xiuwen Wang*, Zhigang Li,Bing Zhao*,Liyan Wang, Wei Kan*, Li Sun, Xin Qi. Construction of hydrophilic covalent organic frameworks and their fast and efficient adsorption towards cationic dyes from aqueous solution,New Journal of Chemistry, 2022, 46, 22185–22194 (DOI: 10.1039/d2nj04336j)
10.Lantian Li,? Anran Li,?Bing Zhao*, Wei Kan*, Chunyu Bi, Wang Zheng, Xiuwen Wang, Li Sun, Liyan Wang and Hongrui Zhang. Multi-sulfonated functionalized hydrophilic covalent organic framework for highly efficient dye removal from real samples, New Journal of Chemistry, 2022, 46, 17016–17025 (DOI: 10.1039/d2nj02857c)
11.李安然,趙冰*,闞偉*,宋天舒,孔祥東,卜凡強(qiáng),孫立,殷廣明,王麗艷.基于菲并咪唑ON?OFF?ON雙比色熒光探針及細(xì)胞成像.高等學(xué)?；瘜W(xué)學(xué)報(bào), 2021, 42(8), 2403–2411 (DOI: 10.7503/cjcu20210089)
12.Jiahui Du,Bing Zhao*, Wei Kan*, Haochun Yin, Tianshu Song, Liyan Wang, Li Sun, Xiuwen Wang, Guangming Yin and Jianxin Wang. A phenanthrene[9,10-d]imidazole-phenol-based fluorescent probe combined ESIPT and AIE for “turn-on” detection of Cu2+with a green-emitting and improved stokes shift and its application.New Journal of Chemistry, 2021, 45(34), 15415–15422 (DOI: 10.1039/D1NJ02177J)
13.Fanqiang Bu,Bing Zhao*, Wei Kan*, Limin Ding*, Ting Liu, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. An ESIPT characteristic “turn-on” fluorescence sensor for Hg2+with large Stokes shift and sequential “turn-off” detection of S2–as well as the application in living cells.Journal of Photochemistry & Photobiology A: Chemistry, 2020, 387, 112165, (DOI: doi.org/10.1016/j.jphotochem.2019.112165).
14.Haochun Yin,Bing Zhao*, Wei Kan*, Limin Ding*, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. A phenanthro[9,10-d]imidazole-based optical sensor for dual-responsive turn-on detection of acidic pH and Cu2+in chicken blood and living cells.Dyes and Pigments, 2020, (173), 107916, (DOI:0.1016/j.dyepig.2019.107916).
15.Yuqian He,Bing Zhao*, Wei Kan*, Limin Ding*, Zhaochuan Yu, Mingyue Wang, Bo Song and Liyan Wang. Two isomeric and distinguishable H2S fluorescence probes for monitoring spoilage of eggs and visualizing exogenous and endogenous H2S in living cells.Analyst, 2020, 145, 213–222 (DOI: 10.1039/c9an01629e).
16.何玉倩，趙冰*，闞偉*，王麗艷，宋波，殷廣明，畢野，陳書文.基于ESIPT和AIE活性的菲并咪唑Fe3+熒光探針及細(xì)胞成像研究.有機(jī)化學(xué)，2019, 39(11), 3250–3257(DOI: 10.6023/cjoc201904078).
17.Bing Zhao *, Yuqian He, Wei Kan *, Fengqiao Kong, Liyan Wang, Bo Song, Wenbo Wang, Guangming Yin, Jianxin Wang. SelectiveN-alkylation of 2-amino-4H-chromene-3-carbonitrile derivatives with alcohols catalyzed by AlCl3under the assistance of CH3COOH,Chemical Research in Chinese Universities, 2019, 35 (6), 997–1001 (DOI: 10.1007/s40242-019-9248-5).
18.Bu Fanqiang,Zhao Bing*, Kan Wei*, Wang Liyan, Song Bo, Wang Jianxin, Zhang Zhe, Deng Qigang, Yin Guangming. A phenanthro[9,10-d]imidazole-based AIE active fluorescence probe for sequential detection of Ag+/AgNPs and SCN–in water and saliva samples and its application in living cells,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.117333).
19.白雨弘旭，趙冰*，何玉倩，楊宜璇，葛薇，陳明明，張立鑫.增強(qiáng)型四苯基咪唑類熒光探針及其對(duì)硫醇的識(shí)別性能.精細(xì)石油化工, 2019,36(4), 79–84.
20.Haochun Yin,Bing Zhao*, Wei Kan*, Ting Liu, Wenbo Wang, Guangming Yin, Wang Liyan, Gao Yan*, Wang Jianxin. Hydroxyl phenyl imino modified phenanthro[9,10-d] imidazole: An AIEE-active sensor for determination of Cu2+in water samples and subsequent "turn-on" recognition of Cr3+with logic gates,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.03.060).
21.Wei Wang, Jian Wu, Qinglei Liu, Gao Yan, Huimin Liu,Bing Zhao. A highly selective coumarin-based chemosensor for the sequential detection of Fe3+and pyrophosphate and its application in living cell imaging.Tetrahedron Letters, 2018, 59(19), 1860–1865.
22.趙冰*，何玉倩，闞偉*，李少鑫，王麗艷，闞宏澤，劉雙義.基于熒光素-羅丹明B的比色探針對(duì)Cu2+和EDTA的接力識(shí)別.精細(xì)石油化工, 2018，35(5), 60–65.
23.李少鑫，闞偉*，趙冰*，李慧婷，王麗艷，劉雙義，闞宏澤.基于熒光素-羅丹明B的雙Schiff堿選擇性紫外識(shí)別Fe3+的探針.精細(xì)石油化工, 2018, 35(2), 58–63.
24.Shaoxin Li, Wei Kan*,Bing Zhao*, Liu Ting, Fang Yue, Bai Liming and Wang Liyan, A fluorescent pH probe for an aqueous solution composed of 7-hydroxycoumarin, Schiff base and phenanthro[9,10-d]imidazole moieties (PICO).Heterocyclic Communications, 2018, 24(2), 93–97 (DOI: 10.1515/hc-2017-0174).
25.Shaoxin Li, Bing Zhao*, Wei Kan, Liyan Wang, Bo Song, and Shuwen Chen*. A off–on pH fluorescence probe derived from phenanthro[9,10-d] imidazol-fluorescein based on ESIPT and ICT,Research on Chemical Intermediates, 2018, 44(1), 491–502. (DOI: 10.1007/s11164-017-3115-0) (IDS No: FS2LC).
26.Bing Zhao *, Ting Liu, Yue Fang, Liyan Wang, Wei Kan, Qigang Deng *, and Bo Song. A new selective chemosensor based on phenanthro[9,10-d] imidazole-coumarin with sequential “on-off-on” fluorescence response to Fe3+and phosphate anions and its application in live cell,Sensors & Actuators: B. Chemical, 2017, 246, 370–379. (DOI: 10.1016/j.snb.2017.02.079).
27.李少鑫，闞偉*，趙冰*，白麗明，劉婷，王麗艷，宋波.氨基乙酰肼鏈接的熒光素-菲并咪唑衍生物的合成與表征.精細(xì)石油化工, 2017, 34(5), 26–31.
28.孔鳳巧，趙冰*，姜黎黎，王麗艷，鄧啟剛.微波輻射下合成1,3-二取代苯基-3-(苯并噻唑-2-氨基)-1-丙酮衍生物.精細(xì)石油化工, 34(3), 2017, 1–7.（2017-05-18）
29.劉婷，趙冰*，李少鑫，房躍，王麗艷，宋波.乙酰氨基鏈接的菲并[9,10-d]咪唑-香豆素衍生物的合成.化學(xué)研究與應(yīng)用, 2017, 29(7), 999–1005.
30.趙冰*，劉婷，王麗艷，鄧啟剛. Schiff堿鏈接的雙菲并咪唑Fe3+熒光探針的合成及識(shí)別性能研究.化學(xué)試劑,2017,39(1),1–5;10.
31.趙冰*，李少鑫，馬明杰，鄧啟剛，王麗艷，闞偉，馮亞青.含乙氧甲酰甲氨基咪唑杯[4]芳烴的合成及其水相體系中對(duì)Al3+和Ag+的熒光識(shí)別.精細(xì)化工,2016,33(10),1189–1194(DOI:10.13550/j.jxhg.2016.10.019 ).
32.Bing Zhao*, Ting Liu, Yue Fang, Liyan Wang, Song Bo and Deng Qigang*. Two “turn-off” Schiff-base fluorescence sensors based on phenanthro [9,10-d]imidazole-coumarin derivatives for Fe3+in aqueous solution,Tetrahedron Letters, 2016, 57(39), 4417–4423 (DOI: 10.1016/j.tetlet.2016.08.064).
33.Bing Zhao*, Yue Fang, Yu Xu, Qigang Deng, Ting Liu, Wei Kan, and Liyan Wang. Dual-responsive pH sensor based on a phenanthro[9,10-d]imidazole fluorophore modified by amino diacetate.Tetrahedron Letters, 2016, 57(16), 1825–1830 (DOI: 10.1016/j.tetlet.2016.03.046).
34.Bing Zhao*, Yu Xu, Qigang Deng, Wei Kan, Yue Fang, Liyan Wang, Yan Gao. Modified 1H-phenanthro[9,10-d]imidazole derivative with the double acetohydrazide as fluorescent probe for sequential detection of Ni2+and Al3+with ‘on–off–on’ response.Tetrahedron Letters, 2016, 57(8), 953–958 (DOI: 10.1016/j.tetlet.2016.01.065)
35.趙冰*，姜黎黎，鄧啟剛，王麗艷，宋波.一鍋三組分合成2取代-1,4-2H-咪唑并[4,5-b]吲哚衍生物.化學(xué)世界,2016,57(1),43–47.
36.Wei Kan, Tao Jing, Xiaohong Zhang, Yongjie Zheng, Lin Chen,Zhao Bing*. Microwave-assisted one pot synthesis ofN-substituted 2-methyl -1H-pyrrole-3-carboxylate derivatives without catalyst and solvent,Heterocycles, 2015, 91(12), 2367–2376 (DOI: 10.3987/COM-15-13340).
37.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng, Liyan Wang, Bo Song, Yan Gao. Microwave-assisted Michael addition of 2-amino pyridine to chalcones under catalyst-free conditions,Research on Chemical Intermediates, 2015, 41, 5809–5819 (DOI: 10.1007/s11164-014-1703-9).
38.Bing Zhao, Yu Xu, Mingjie Ma, Qigang Deng. A selective fluorescence probe for copper(II) ion in aqueous solution based on 4-(1,4,5-triphenyl-1H-imidazol-2- yl)anilinyl acetates,Research on Chemical Intermediates, 2015, 41, 8031–8040 (DOI: 10.1007/s11164-014-1875-3).
39.Bing Zhao, Yue Fang, Mingjie Ma, Qigang Deng, Yu Xu, Liyan Wang. A new on-fluorescent sensor for Ag+based on benzimidazole bearing bis(ethoxycarbonyl methyl)amino groups.Heterocyclic Communications, 2015, 21(4), 211–214 (DOI: 10.1515/hc-2015-0002).
40.Bing Zhao, Yu Xu, Yue Fang, Liyan Wang Qigang, Deng. Synthesis and fluorescence properties of phenanthro[9,10-d] imidazole derivative for Ag+in aqueous media.Tetrahedron Letters, 56(19), 2015, 2460–2465. (DOI: 10.1016/j.tetlet.2015.03.094).
41.趙冰,馬明杰,阮耀宇,王麗艷,闞偉,宋波,石克炘.含氨基乙酸酯苯并咪唑杯[4]芳烴熒光分子探針的合成及光譜性能.化學(xué)試劑, 2015,37（6）,545–548；560.
42.Bing Zhao, Yu Xu, Qigang Deng, Zhuo Liu, Liyan Wang, Yan Gao. One-pot, three component synthesis of novel 5H-[1,3,4]thiadiazolo[3,2-a]pyrimidine- 6-carboxylate derivatives by microwave irradiation.Tetrahedron Letters, 2014, 55(33), 4521–4524 (DOI: 10.1016/j.tetlet.2014.06.073).
43.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng*, Liyan Wang, Song Bo, and Gao Yan, A microwave assisted synthesis of highly substituted 7-methyl- 5H-thiazole[3,2-a]pyridmidine -6-carboxylate derivatives via one pot reaction of aminothiazole, aldehyde and ethyl acetoacetate.Heterocycles, 87(10), 2013, 2093–2102 (DOI: 10.3987/COM-13-12797)
44.Bing Zhao, Yaoyu Ruan, Mingjie Ma, Qigang Deng*, Liyan Wang, Yaqing Feng, and Yan Gao. One-pot synthesis of 11,23-bis(imidazol-1-yl)calix[4]arene derivatives based on the upper rim of bis-aminocalix[4]arene.Heterocycles, 2013, 87(9), 1917–1924 (DOI: 10.3987/COM-13-12771).
45.Bing Zhao, Yacui Zhou, Mengjiao Fan, Zhiyu Li, Liyan Wang, Qigang Deng. Synthesis, fluorescence properties and selective Cr(III) recognition of tetraaryl imidazole derivatives bearing thiazole group.Chinese Chemical Letters, 2013, 24, 257–259 (DOI: 10.1016/j.cclet.2013.01.031).
46.Bing Zhao, Yaoyu Ruan, Qigang Deng, Liyan Wang, Bo Song and Yaqing Feng. Synthesis and characterization of heteroarylthio derivatives of 5, 17-di-tert-butyl-11, 23-diamido-25, 27-diprotected calix[4]arene.Heterocyclic Communication, 2013, 1, 19–22 (DOI: 10.1515/hc-2012-0154).
47.Bing Zhao, Mengjiao Fan, Zhuo Liu, Lifeng Hu, Bo Song, Liyan Wang and Qigang Deng.Reformatsky reaction promoted by an ionic liquid ([Bmim]Cl) in the synthesis ofβ-hydroxyl ketone derivatives bearing a coumarin unit,Journal of Chemical Research, 2012, 6, 393–395 (DOI: 10.3184/174751912X13371 652436057).
科研項(xiàng)目
1.硫酸鉀制粒項(xiàng)目實(shí)施關(guān)鍵技術(shù)攻關(guān)與轉(zhuǎn)化，項(xiàng)目負(fù)責(zé)人，黑龍江省省屬高等學(xué)?；究蒲袠I(yè)務(wù)費(fèi)科研項(xiàng)目，2023—2025。
2.新型“雙響應(yīng)”熒光共價(jià)有機(jī)框架的構(gòu)建及響應(yīng)機(jī)制研究，項(xiàng)目負(fù)責(zé)人，國(guó)家自然科學(xué)基金面上項(xiàng)目，2021—2024。
3.熒光型共價(jià)有機(jī)框架材料的設(shè)計(jì)及生物學(xué)響應(yīng)特征研究，項(xiàng)目負(fù)責(zé)人，黑龍江省重點(diǎn)研發(fā)計(jì)劃指導(dǎo)項(xiàng)目，2021—2023。
4.基于AIEE和ESIPT的菲并咪唑白光探針的設(shè)計(jì)和性能研究，項(xiàng)目負(fù)責(zé)人，黑龍江省級(jí)領(lǐng)軍人才梯隊(duì)后備帶頭人資助項(xiàng)目，2018—2021。
5.基于多重響應(yīng)機(jī)理協(xié)同作用的雙光子熒光探針的合成及識(shí)別性能研究，項(xiàng)目負(fù)責(zé)人，黑龍江省省屬高等學(xué)?；究蒲袠I(yè)務(wù)費(fèi)科研項(xiàng)目，2018—2020。
6.基于熒光探針?lè)z測(cè)酒類飲品中Cu2+含量的研究，項(xiàng)目負(fù)責(zé)人，黑龍江省省屬高等學(xué)?；究蒲袠I(yè)務(wù)費(fèi)科研項(xiàng)目（植物性食品加工技術(shù)特色學(xué)科專項(xiàng)），2018—2020。
7.基于稠(多)芳基咪唑tweezers結(jié)構(gòu)熒光分子的構(gòu)建及其識(shí)別性能研究，項(xiàng)目負(fù)責(zé)人，黑龍江省科學(xué)基金留學(xué)歸國(guó)人員科學(xué)基金項(xiàng)目，2017—2020。
8.基于稠環(huán)及多芳基咪唑長(zhǎng)波長(zhǎng)熒光分子探針的設(shè)計(jì)及接力識(shí)別性能研究，項(xiàng)目負(fù)責(zé)人，國(guó)家自然基金青年科學(xué)基金項(xiàng)目，2016—2018。
9.基于杯芳烴的多芳基咪唑雙功能熒光分子探針的設(shè)計(jì)合成及性能研究，項(xiàng)目負(fù)責(zé)人，黑龍江教育廳面上項(xiàng)目，2014—2015。
10.雜環(huán)硫乙酰氨類杯[4]芳烴衍生物的合成及離子識(shí)別性能的研究，項(xiàng)目負(fù)責(zé)人，黑龍江省科技廳青年基金項(xiàng)目，2010—2012。
專利
1.趙冰，李秋爽，李元琪，李蘭天，闞偉，王麗艷，王秀文，孫立，杜研，沈思宇，沈曉亮。一種雜原子摻雜共價(jià)有機(jī)框架材料及其制備方法與應(yīng)用，發(fā)明專利，專利號(hào)ZL 2022 1 0842324.4，授權(quán)日期2024.02。
2.趙冰，卜凡強(qiáng)，宋天舒，闞偉，王文波，殷廣明，王麗艷。一種裸眼或熒光檢測(cè)Ag+雙菲并咪唑探針及使用方法，發(fā)明專利，專利號(hào)ZL201811192860.4，授權(quán)日期2021.01。
3.趙冰，卜凡強(qiáng)。一種裸眼或熒光Al3+探針及其制備方法和應(yīng)用，發(fā)明專利，ZL 201911000088.6，授權(quán)日期2023.09。
4.趙冰，李秋爽，李元琪，孔祥東，闞偉，王麗艷，王秀文，孫立，杜研，沈思宇，沈曉亮。一種Cu2+和Al3+雙功能熒光共價(jià)有機(jī)框架材料及其制備方法和應(yīng)用，發(fā)明專利，ZL 2022 1 0740307.X，授權(quán)日期2023.07。
5.趙冰，鄭旺，李志剛，趙立杰，闞偉，王麗艷，孫立，王秀文。一種用于對(duì)苯二酚吸附的共價(jià)有機(jī)框架材料及其制備方法和應(yīng)用，發(fā)明專利，ZL202111515003.5，授權(quán)日期2023.06。
6.趙冰，李志剛，闞偉，李安然，鄭旺，卜凡強(qiáng)，王麗艷，宋波，孫立，王秀文。一種實(shí)時(shí)檢測(cè)亞硫酸氫根離子的熒光探針及其制備方法與應(yīng)用，發(fā)明專利，ZL 202111542466.0，授權(quán)日期2023.03。
7.趙冰，李安然，孔祥東，杜佳慧，闞偉，卜凡強(qiáng)，王麗艷，孫立，王秀文。一種光譜法和比色法檢測(cè)不同形式碘的分子平臺(tái)及其制備方法和應(yīng)用，發(fā)明專利，ZL202010794666.4，授權(quán)日期2022.08。
8.趙冰，宋天舒，李安然，孔祥東，闞偉，王麗艷，孫立，王秀文。一種Cu2+熒光共價(jià)有機(jī)框架材料及其制備和應(yīng)用，發(fā)明專利，ZL 202110170647.9，授權(quán)日期2022.06。
9.趙冰，卜凡強(qiáng)，宋天舒，闞偉，王文波，殷廣明，王麗艷。一種裸眼或熒光檢測(cè)Ag+雙菲并咪唑探針及使用方法，發(fā)明專利，ZL2018 1 1192860.4，授權(quán)日期2021.01。
10.趙冰，劉婷，孔鳳巧，李少鑫，闞偉，王麗艷。可逆雙羥基菲并咪唑Hg2+熒光探針及其合成與使用方法，發(fā)明專利，ZL201611019074.5，授權(quán)日期2020.08。
11.趙冰，孔鳳巧，卜凡強(qiáng)，李少鑫，劉婷，王麗艷，闞偉，宋波。一種Lewis/Bronsted酸促進(jìn)下醇參與的2-氨基色烯衍生物N-烷基化方法，發(fā)明專利，專利號(hào)ZL201710255046.1，授權(quán)日期2019.06。
12.趙冰，卜凡強(qiáng)，何玉倩，李少鑫，尹浩純，闞偉，王麗艷。一種用于裸眼檢測(cè)的熒光素-羅丹明B銅離子紫外分子探針及其合成和使用方法，發(fā)明專利，專利號(hào)ZL201711088730.1，授權(quán)日期2019.05。
13.趙冰，宋波，李少鑫，孔鳳巧，劉婷，闞偉，王麗艷。三羥基咪唑-熒光素pH熒光探針及其制備方法，發(fā)明專利，專利號(hào)ZL201611047563.1，授權(quán)日期2019.05。
14.趙冰，劉婷，鄧啟剛，王麗艷，闞偉，宋波。雙Schiff堿鏈接的對(duì)稱型菲并咪唑Fe3+熒光探針及制備方法，發(fā)明專利，專利號(hào)ZL201610201233.7，授權(quán)日期2017.09。
15.趙冰。一種用于鐵離子檢測(cè)的菲并咪唑-香豆素雙熒光基團(tuán)比率熒光分子探針及其合成和使用方法，發(fā)明專利，專利號(hào)ZL201510785171.4，授權(quán)日期2017.04。
16.趙冰，阮耀宇，闞偉，王麗艷，鄧啟剛。一種多取代咪唑杯芳烴衍生物及制備方法，發(fā)明專利，專利號(hào)ZL 201310015856.1，授權(quán)日期2015.09。
17.趙冰，闞偉，劉卓，王麗艷，宋波，鄧啟剛。一鍋法合成噻唑并[3,2-a]嘧啶類衍生物的方法，發(fā)明專利，專利號(hào)ZL201310016623.3，授權(quán)日期2015.04。
18.趙冰，闞偉，劉卓，王麗艷，鄧啟剛。一種多取代噻二唑并[3,2-a]嘧啶-6-羧酸酯衍生物的微波合成方法，發(fā)明專利，專利號(hào)ZL201310052797.5，授權(quán)日期2015.02。
19.鄧啟剛，陳朝暉，趙冰。一種亞麻織物后整理工藝，發(fā)明專利，專利號(hào)ZL 2009 1 0071368，授權(quán)日期2012.08。
專著或教材
1.宋波，闞偉，趙冰.淀粉化學(xué)品，哈爾濱工程大學(xué)出版社，2009.08。
2.趙冰.有機(jī)化學(xué)反應(yīng)與有機(jī)材料研究，中國(guó)水利水電出版社，2014.10。
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